Rhodium(I)-centered cyclotriveratrylene
نویسندگان
چکیده
منابع مشابه
Hydrogelators of cyclotriveratrylene derivatives.
Developing cavity-based supramolecular hydrogels is in its infancy because not many such hydrogelators are available. Reported herein is our creation of rigid cavitand cyclotriveratrylene (CTV) based hydrogelators from the molecular backbones of CTVs that were in limited cases shown to form organogels. For doing so deprotonable -COOH or protonable -NH(2) was introduced as terminal group into th...
متن کاملRearrangement of cyclotriveratrylene (CTV) diketone: 9,10-diarylanthracenes with OLED applications.
Electroluminescent 9,10-diaryl anthracenes have been shown to be promising host and hole-transporting materials in organic electroluminescence due to their high thermal stability, electrochemical reversibility, and wide band gap useful for organic light-emitting diodes (OLEDs), especially blue OLEDs. Oxidation of cyclotriveratrylene (CTV) to the corresponding diketone and subsequent bromination...
متن کاملTwo guest complexation modes in a cyclotriveratrylene-based molecular container.
We report the synthesis of a cyclotriveratrylene-based molecular container and its distinctly different modes of complexation with dimethyldiazapyrenium and 4,4'-biphenylbisdiazonium ions.
متن کاملSyntheses of Cyclotriveratrylene Analogues and Their Long Elusive Triketone Congeners
Although interest in cyclotriveratrylene and its analogues has been significant, limitations in the ability to adjust its structure fully have hampered studies into their complete range of properties. A unique strategy to synthesize a previously unobtainable cyclotriveratrylene analogue and a procedure which adjusts the inner methylene bridges of that material to a triketone is reported. A seco...
متن کاملDirect patterning of a cyclotriveratrylene derivative for directed self-assembly of C60.
A novel apex-modified cyclotriveratrylene (CTV) derivative with an attached thiolane-containing lipoic acid linker was directly patterned onto gold substrates via dip-pen nanolithography (DPN). The addition of a dithiolane-containing linker to the apex of CTV provides a molecule that can adhere to a gold surface with its bowl-shaped cavity directed away from the surface, thereby providing a sur...
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ژورنال
عنوان ژورنال: Recueil des Travaux Chimiques des Pays-Bas
سال: 2010
ISSN: 0165-0513
DOI: 10.1002/recl.19951140902